When the consumed sulphur in coal is in the form of sulphur dioxide at the end of combustion, it reacts with water at high altitudes. Moreover, it goes down to the earth in the form of sulphuric acid, as well as damaging plants. The corrosive harmful impact on industrial plants is the removal of the sulphur in the coal when it is environmental.
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Hot coal gas desulfurization process operating at elevated temperature (600850 °C) is an efficient and environmentally friendly process for raw syngas purification (Tamhankar et al. 1986). The sketch of hot coal gas desulfurization process is depicted in Fig. 1. Coal was gasified at temperatures of > 1000 °C to produce raw syngas (~ 850 ...
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Desulfurization systems in coalfired power stations often suffer the problem of high operating costs caused by a ruleofthumb control strategy, which implies great potential for optimization of the operation. ... In this paper, an operation strategy optimization method for the desulfurization process is proposed based on a data mining ...
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The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
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The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation.
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Coal desulfurization The development and utilization of traditional coal plays a vital role in promoting social and economic development, but it has brought irreversible pollution to the ecological environment ( Zeng et al., 2021 ).
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Flue gas desulfurization (FGD) systems using lime or limestone as the chemical reagent are widely used throughout the world for SO 2 emissions control at coalfired power plants. Ammoniabased ...
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In addition, the photocatalytic desulfurization process has little effect on the heat value of coal. On a basis of TGDSCDDSC analysis, it is found that the calorific value of the coal after photocatalytic desulfurization was slightly changed and the low temperature oxidation tendency was decreased which is helpful for desulfurized coal storage.
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Most of the effective coal desulfurization techniques are based on chemical methods. Main desulfurization methods are chemical desulfurization, leaching, extraction, flotation, oxydesulfurization and biodesulfurization. The alkaline desulfurization is more effective in removing the pyritic sulfur from the coal, which is the less abundant form ...
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The combined effect of desulfurization and ash removal in the process of coal desulfurization by microwave with peroxyacetic acid was determined by evaluating variations in minerals and sulfur forms using Xray diffraction and Xray photoelectron spectroscopy. Dielectric properties of minerals or organic sulfur functional groups in coal were studied utilizing a vector network analyzer in the ...
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This study investigated the characteristics of mercury emitted from a largescale coalfired power plant in Taiwan via intensive sampling campaigns. The air pollution control devices equipped in this coalfired power plant include selective catalytic reduction, fabric filter and seawater flue gas desulfurization. During three sampling campaigns, mercury concentrations emitted from this large ...
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... In the wet desulfurization process, the scaling and blockage of equipment are easy to occur in the process site. In view of the above problems, a calciumsodium ...
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In coal combustion, to generate electric power and process heat, the sulfur is emitted as SO2, which is seen as one of the main causes of acid rain. This effect has led to an interest in the three main methods of removing coal sulfur: coal cleaning, inbed desulfurization, and flue gas desulfurization. Coal cleaning includes physical, chemical,
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XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
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As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect. Hence, the comprehensive moisture ...
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Abstract. Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Due to its abundance, chemical and physical properties, FGDG has been used in several beneficial applications. However, during the past decade, the rate of beneficially used FGDG has ...
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In addition, the sulfur content of the raw coal reduces from % to %, total desulfurization rate of %, whose organic sulfur desulfurization is % after coal in shake flask experiments. And the desulfurization rate approaches the maximum value on the tenth day (from Figure 2B). It was demonstrated that strain SX12 could ...
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Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Flue gas desulfurization systems have been used to limit the release of sulfur dioxide from coalfired power plants since the late 1960s, but in the past decade the production of FGDG has ...
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A novel method for the chemical desulfurization of coal in relatively moderate conditions and short times is presented. Using concentrated hydroiodic acid as a desulfurizing agent and microwaves as the energy source, sulfate and pyritic sulfur are completely removed in 10 min. Moreover, for the lowrank coals studied, variable amounts of organic sulfur, up to 70% in 20 min, can be removed, for ...
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Coal desulfurization by microwave with additives has been investigated in many aspects, including desulfurization effects [38], coal property changes [39], sulfur species and dielectric characteristics [27,40]. ... XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave ...
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The present work describes the desulfurization of coal using mildly reductive method. Both a Yanzhou and a Yanshan coal (referred to as YZ and YS coal, respectively), were treated in an aqueous media employing sodium borohydride (NaBH 4) as reducing agent, which is a well known hydrogen variables investigated include concentration of reductant, time, pH of initial media ...
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In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. ... In this study, a highsulfur coal desulfurization experiment was carried out for highsulfur raw coal to reveal the internal ...
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Desulfurization of Coal by Pyrolysis and Hydropyrolysis with Addition of KOH/NaOH Quanrun Liu, Haoquan Hu, Shengwei Zhu, Qiang Zhou, Wenying Li, Xianyong Wei, and Kechang Xie View Author Information Cite this: Energy Fuels 2005, 19, 4, Publication Date: April 23, 2005 https:////ef
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Before and after the desulfurization process; total sulfur, pyritic sulfur, carbon content and calorific value were measured. The highest removal efficiencies of total sulfur and pyritic sulfur for Burdur coal obtained as 41% and 67%, for Tunçbilek coal obtained as 41% and 35%, and for Ermenek coal obtained as 47% and 41%, respectively.
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The Energy Information Administration estimates (as of October 2022) that in 2021, CO 2 emissions from burning coal for energy accounted for about 20% of total energyrelated CO 2 emissions and for nearly 60% of total CO 2 emissions from the electric power sector. In the past, fly ash was released into the air through the smokestack ...
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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