WEBDec 21, 2004 · The processes for deformation of hBN structure during ball milling are accordingly divided into three steps as follows: For shorter milling durations (for 1 h using a planetary ball mill [32] or ...
WhatsApp: +86 18203695377WEBMay 27, 2020 · In this study, the putative correlation between the molecular mobility of a polymer and the ball milling drug amorphization kinetics (, time to reach full drug amorphization, ta) was studied using different grades of dextran (Dex) and polyvinylpyrrolidone (PVP) and the two model drugs indomethacin (IND) and .
WhatsApp: +86 18203695377WEBJun 27, 2019 · Abstract This study investigated the characteristics of cellulose Avicel PH101 (NPA) and Avicel samples treated by either ball milling (BMA) or ionic liquid 1ethyl3methylimidazolium acetate (ILA), which alter cellulose structural properties specifically and, consequently, affect the enzymatic hydrolysis of these materials differently. All materials .
WhatsApp: +86 18203695377WEBApr 15, 2017 · Amorphization in metallic systems (intermetallic compounds, metallic multilayers, metallic solid solutions) has been produced by different means such as solidstate reaction [85], pressure [86], [87], ball milling [88], [89], cold plastic deformation [90], and irradiation [91], [92]. The common ground of amorphization by solid state reaction ...
WhatsApp: +86 18203695377WEBStructural changes occurring in the crystalline element selenium upon highenergy ball milling has been studied. Milling experiments have been performed at the ambient temperature and at a cryogenic temperature of 100 degrees C, respectively. The final milling products under both conditions were found to be a fully amorphous phase after .
WhatsApp: +86 18203695377WEBAug 23, 2021 · Amorphization technology has been the subject of continuous attention in the pharmaceutical industry, as a means to enhance the solubility of poorly watersoluble drugs. Being in a high energy state, amorphous formulations generally display significantly increased apparent solubility as compared to their crystalline counterparts, which may .
WhatsApp: +86 18203695377WEBThe fracture energy E t per unit time of ball milling is given by [4] (1) E t ∝ W 2 · v 3 · d1 where W is the total weight of the ball milling media, v is the average velocity of the media in motion, and d is the ball diameter of the media. Herein, small zirconia beads with a high specific gravity were selected as the ball milling media.
WhatsApp: +86 18203695377WEBDec 29, 2016 · After 48 h of ball milling, the homogenous mixtures of supersaturated nanocrystalline solid solution of Fe (Dy, O) and Dy2O3 amorphization were formed and the elements of Fe, Dy, and O were distributed uniformly in the ballmilled particles.
WhatsApp: +86 18203695377WEBXray diffraction has been used to investigate the kinetics of amorphization through ballmilling at 20 Hz, for five zeolitic imidazolate frameworks (ZIFs) and shows thatAmorphous ZIFzni is structurally indistinguishable from amorphous CdIF1 with both structures retaining the same shortrange order that is present in their crystalline precursors.
WhatsApp: +86 18203695377WEBMar 23, 2023 · The amorphization of 18 different drugs on milling with one mole equiv. sodium taurocholate (NaTC) was investigated. In all cases the Xray powder pattern showed an amorphous halo after milling at room temp. or after cryomilling and 14 of the 18 coamorphous drugNaTC systems were phys. stable for between one to eleven months .
WhatsApp: +86 18203695377WEBJul 1, 1993 · It is found that Ni x Zr y compounds become fully amorphized provided the specific milling intensity is greater than a temperature and compositiondependent threshold value. A vibrating frame grinder has been instrumented for evaluating the amplitude and frequency of ball oscillation, as a function of the amplitude of vibration of .
WhatsApp: +86 18203695377WEBJan 31, 2011 · The microstructure of NiZr 2 in the course of amorphization by ballmilling is studied by transmission electron microscopy (TEM) and xray diffraction (XRD). The evolution from the initial fully crystalline alloy to a fully amorphized material is described. It is shown that prior to amorphization, the powder aggregates achieve a .
WhatsApp: +86 18203695377WEBJul 11, 2012 · The rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF8, by ballmilling is reported, which possesses a continuous random network topology with a higher density and a lower porosity than its crystalline counterpart. We report the rapid amorphization of the prototypical substituted zeolitic imidazolate .
WhatsApp: +86 18203695377WEBMay 1, 2003 · CRMA by ball milling was carried out in the magnetomill, UniBallMill 5 ( Scientific Engineering Pty Ltd., Australia) [5][6][7][8] [9]. The milling mode in this magnetomill was adjusted ...
WhatsApp: +86 18203695377WEBSemantic Scholar extracted view of "Amorphization of single composition powders by mechanical milling" by C. Koch
WhatsApp: +86 18203695377WEBAmorphization of ZIF8 and another isostructural MOF, ZIFmnIm (Zn(mnIm) 2 where mnIm = 4methyl5nitroimidazolate), during ball milling 85 also significantly enhances their iodine retention abilities, particularly in the case of ZIFmnIm.
WhatsApp: +86 18203695377WEBJul 1, 1990 · Amorphization by ball milling. A review. Article. Oct 1988; PHYSICA B; Weeber; H. Bakker; A new method for the preparation of amorphous alloys is the mechanical alloying process. So far ...
WhatsApp: +86 18203695377WEBJul 25, 2022 · In this paper, we show that the polymorphic transformation γ → α of sorbitol upon milling involves a transient amorphization of the material. This could be done by comilling sorbitol with a high Tg amorphous material (Hydrochlorothiazide, Tg = 115 °C) to stabilize any transient amorphous fractions of sorbitol through the formation of a .
WhatsApp: +86 18203695377WEBJan 31, 2011 · An intermetallic compound c–NiZr and a mixture of elemental powders of nickel and zirconium [Ni50Zr50 (at. %)] have been mechanically ground (MG) and mechanically alloyed (MA), respectively, using a highenergy ball mill in various atmospheres. The products were characterized by xray diffraction, transmission .
WhatsApp: +86 18203695377WEBFeb 27, 2021 · Longtime ball milling and bead milling will also reduce the purity of Si particles because of the wear loss of balls or beads ... Si particles undergo a process from amorphization at hightemperature to recrystallization at rapidly cooling. The repeated impacts in the bead milling process further refine the grains and generate amorphous ...
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